Vasco have now won five of their nine matches to date this season and are three points behind leaders Internacional, who lost 1-0 at Goias earlier on Sunday. Botafogo are 17th with just nine points.
After that, Osaka dominated and claimed the set 6-3.
On the other side of Manchester, Ole Gunnar Solskjaer can be reasonably satisfied after a season that looked destined to end in total mediocrity finished with a third-place finish and a Europa League semi-final appearance.
Although the process is quite tough, the Asian junior record holder still firmly believes that he can return to his best form soon.
The "BVB" smoothed the way for their win with three first-half goals, while Dominic Volkmer's red card before half-time left Duisburg hopeless.
The rivalry between the two clubs is one of the biggest in Ligue 1, which is also related to the competition of the two cities, the biggest and second-biggest in the country.
"I was super close to being a grand slam champion. I was a few games away, maybe a few points away. For me what upset me the most is not the third set or something like that, it's the fifth set. I had a lot of chances in the fifth set and didn't use them," said a disappointed Zverev, who was contesting his first career major final.
In other matches on Sunday, Atletico Goianiense won 1-0 at Bahia, Atletico Mineiro secured a 2-1 home win against Bragantino and Fortaleza drew 1-1 at Gremio. Enditem
However, Molders remained in the thick of things and headed onto the crossbar moments later.
Marcos Alves broke the deadlock for Hebei in the 15th minute through a header after receiving Yin Hongbo's long pass.
Ten minutes later, Spanish midfielder Nono curved the ball beautifully over the wall on a set-piece and Dobrivoj Rusov had to fish the ball out of his net for the second and final time.